Beilstein J. Org. Chem.2024,20, 479–496, doi:10.3762/bjoc.20.43
both within the context of a classic gold π-activation/protodeauration mechanism and a general acid-catalyzed mechanism without intermediate gold alkyls.
Keywords: alkene hydroamination; general acid catalysis; gold catalysis; isotope effect; phosphineligandeffect; solvent effect; Introduction
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Graphical Abstract
Scheme 1:
Proposed mechanism and observation of alkylgold intermediates.